One-Pot Conversion of Cyclohexane to Adipic Acid Using aμ4-Oxido-Copper Cluster as Catalyst Together with HydrogenPeroxide
- The production of nylon-6.6 is one of the largest scale syntheses in industrial chemistry. The standard procedure is based on an energy consuming low-level conversion of cyclohexane to yield adipic acid in two steps that is converted to nylon-6.6 in a separate step. Therefore, there is a strong intent to optimize the synthetic route in an economic and ecologic matter. In this work, we present a one-pot oxygenation of cyclohexane with hydrogen peroxide and a µ4-oxido-copper cluster catalyst to yield dicarboxylic acids with adipic acid as the main product.
Author: | Christopher Gawlig, Siegfried Schindler, Sabine Becker |
---|---|
URN: | urn:nbn:de:hbz:386-kluedo-79576 |
DOI: | https://doi.org/10.1002/ejic.201901052 |
ISSN: | 1099-0682 |
Parent Title (English): | European Journal of Inorganic Chemistry |
Publisher: | Wiley |
Document Type: | Article |
Language of publication: | English |
Date of Publication (online): | 2024/04/05 |
Year of first Publication: | 2019 |
Publishing Institution: | Rheinland-Pfälzische Technische Universität Kaiserslautern-Landau |
Date of the Publication (Server): | 2024/04/05 |
Issue: | 3 |
Page Number: | 5 |
First Page: | 248 |
Last Page: | 252 |
Source: | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201901052 |
Faculties / Organisational entities: | Kaiserslautern - Fachbereich Chemie |
DDC-Cassification: | 5 Naturwissenschaften und Mathematik / 540 Chemie |
Collections: | Open-Access-Publikationsfonds |
Licence (German): | Zweitveröffentlichung |