## Dissertation

### Filtern

#### Erscheinungsjahr

- 2005 (29) (entfernen)

#### Dokumenttyp

- Dissertation (29) (entfernen)

#### Sprache

- Englisch (29) (entfernen)

#### Schlagworte

#### Fachbereich / Organisatorische Einheit

Channel estimation is of great importance in many wireless communication systems, since it influences the overall performance of a system significantly. Especially in multi-user and/or multi-antenna systems, i.e. generally in multi-branch systems, the requirements on channel estimation are very high, since the training signals or so called pilots that are used for channel estimation suffer from multiple access interference. Recently, in the context with such systems more and more attention is paid to concepts for joint channel estimation (JCE) which have the capability to eliminate the multiple access interference and also the interference between the channel coefficients. The performance of JCE can be evaluated in noise limited systems by the SNR degradation and in interference limited systems by the variation coefficient. Theoretical analysis carried out in this thesis verifies that both performance criteria are closely related to the patterns of the pilots used for JCE, no matter the signals are represented in the time domain or in the frequency domain. Optimum pilots like disjoint pilots, Walsh code based pilots or CAZAC code based pilots, whose constructions are described in this thesis, do not show any SNR degradation when being applied to multi-branch systems. It is shown that optimum pilots constructed in the time domain become optimum pilots in the frequency domain after a discrete Fourier transformation. Correspondingly, optimum pilots in the frequency domain become optimum pilots in the time domain after an inverse discrete Fourier transformation. However, even for optimum pilots different variation coefficients are obtained in interference limited systems. Furthermore, especially for OFDM-based transmission schemes the peak-to-average power ratio (PAPR) of the transmit signal is an important decision criteria for choosing the most suitable pilots. CAZAC code based pilots are the only pilots among the regarded pilot constructions that result in a PAPR of 0 dB for the transmit signal that origins in the transmitted pilots. When summarizing the analysis regarding the SNR degradation, the variation coefficient and the PAPR with respect to one single service area and considering the impact due to interference from other adjacent service areas that occur due to a certain choice of the pilots, one can conclude that CAZAC codes are the most suitable pilots for the application in JCE of multi-carrier multi-branch systems, especially in the case if CAZAC codes that origin in different mother codes are assigned to different adjacent service areas. The theoretical results of the thesis are verified by simulation results. The choice of the parameters for the frequency domain or time domain JCE is oriented towards the evaluated implementation complexity. According to the chosen parameterization of the regarded OFDM-based and FMT-based systems it is shown that a frequency domain JCE is the best choice for OFDM and a time domain JCE is the best choice for FMT applying CAZAC codes as pilots. The results of this thesis can be used as a basis for further theoretical research and also for future JCE implementation in wireless systems.

This thesis contains the mathematical treatment of a special class of analog microelectronic circuits called translinear circuits. The goal is to provide foundations of a new coherent synthesis approach for this class of circuits. The mathematical methods of the suggested synthesis approach come from graph theory, combinatorics, and from algebraic geometry, in particular symbolic methods from computer algebra. Translinear circuits form a very special class of analog circuits, because they rely on nonlinear device models, but still allow a very structured approach to network analysis and synthesis. Thus, translinear circuits play the role of a bridge between the "unknown space" of nonlinear circuit theory and the very well exploited domain of linear circuit theory. The nonlinear equations describing the behavior of translinear circuits possess a strong algebraic structure that is nonetheless flexible enough for a wide range of nonlinear functionality. Furthermore, translinear circuits offer several technical advantages like high functional density, low supply voltage and insensitivity to temperature. This unique profile is the reason that several authors consider translinear networks as the key to systematic synthesis methods for nonlinear circuits. The thesis proposes the usage of a computer-generated catalog of translinear network topologies as a synthesis tool. The idea to compile such a catalog has grown from the observation that on the one hand, the topology of a translinear network must satisfy strong constraints which severely limit the number of "admissible" topologies, in particular for networks with few transistors, and on the other hand, the topology of a translinear network already fixes its essential behavior, at least for static networks, because the so-called translinear principle requires the continuous parameters of all transistors to be the same. Even though the admissible topologies are heavily restricted, it is a highly nontrivial task to compile such a catalog. Combinatorial techniques have been adapted to undertake this task. In a catalog of translinear network topologies, prototype network equations can be stored along with each topology. When a circuit with a specified behavior is to be designed, one can search the catalog for a network whose equations can be matched with the desired behavior. In this context, two algebraic problems arise: To set up a meaningful equation for a network in the catalog, an elimination of variables must be performed, and to test whether a prototype equation from the catalog and a specified equation of desired behavior can be "matched", a complex system of polynomial equations must be solved, where the solutions are restricted to a finite set of integers. Sophisticated algorithms from computer algebra are applied in both cases to perform the symbolic computations. All mentioned algorithms have been implemented using C++, Singular, and Mathematica, and are successfully applied to actual design problems of humidity sensor circuitry at Analog Microelectronics GmbH, Mainz. As result of the research conducted, an exhaustive catalog of all static formal translinear networks with at most eight transistors is available. The application for the humidity sensor system proves the applicability of the developed synthesis approach. The details and implementations of the algorithms are worked out only for static networks, but can easily be adopted for dynamic networks as well. While the implementation of the combinatorial algorithms is stand-alone software written "from scratch" in C++, the implementation of the algebraic algorithms, namely the symbolic treatment of the network equations and the match finding, heavily rely on the sophisticated Gröbner basis engine of Singular and thus on more than a decade of experience contained in a special-purpose computer algebra system. It should be pointed out that the thesis contains the new observation that the translinear loop equations of a translinear network are precisely represented by the toric ideal of the network's translinear digraph. Altogether, this thesis confirms and strengthenes the key role of translinear circuits as systematically designable nonlinear circuits.

Automated theorem proving is a search problem and, by its undecidability, a very difficult one. The challenge in the development of a practically successful prover is the mapping of the extensively developed theory into a program that runs efficiently on a computer. Starting from a level-based system model for automated theorem provers, in this work we present different techniques that are important for the development of powerful equational theorem provers. The contributions can be divided into three areas: Architecture. We present a novel prover architecture that is based on a set-based compression scheme. With moderate additional computational costs we achieve a substantial reduction of the memory requirements. Further wins are architectural clarity, the easy provision of proof objects, and a new way to parallelize a prover which shows respectable speed-ups in practice. The compact representation paves the way to new applications of automated equational provers in the area of verification systems. Algorithms. To improve the speed of a prover we need efficient solutions for the most time-consuming sub-tasks. We demonstrate improvements of several orders of magnitude for two of the most widely used term orderings, LPO and KBO. Other important contributions are a novel generic unsatisfiability test for ordering constraints and, based on that, a sufficient ground reducibility criterion with an excellent cost-benefit ratio. Redundancy avoidance. The notion of redundancy is of central importance to justify simplifying inferences which are used to prune the search space. In our experience with unfailing completion, the usual notion of redundancy is not strong enough. In the presence of associativity and commutativity, the provers often get stuck enumerating equations that are permutations of each other. By extending and refining the proof ordering, many more equations can be shown redundant. Furthermore, our refinement of the unfailing completion approach allows us to use redundant equations for simplification without the need to consider them for generating inferences. We describe the efficient implementation of several redundancy criteria and experimentally investigate their influence on the proof search. The combination of these techniques results in a considerable improvement of the practical performance of a prover, which we demonstrate with extensive experiments for the automated theorem prover Waldmeister. The progress achieved allows the prover to solve problems that were previously out of reach. This considerably enhances the potential of the prover and opens up the way for new applications.

Over the last decades, mathematical modeling has reached nearly all fields of natural science. The abstraction and reduction to a mathematical model has proven to be a powerful tool to gain a deeper insight into physical and technical processes. The increasing computing power has made numerical simulations available for many industrial applications. In recent years, mathematicians and engineers have turned there attention to model solid materials. New challenges have been found in the simulation of solids and fluid-structure interactions. In this context, it is indispensable to study the dynamics of elastic solids. Elasticity is a main feature of solid bodies while demanding a great deal of the numerical treatment. There exists a multitude of commercial tools to simulate the behavior of elastic solids. Anyhow, the majority of these software packages consider quasi-stationary problems. In the present work, we are interested in highly dynamical problems, e.g. the rotation of a solid. The applicability to free-boundary problems is a further emphasis of our considerations. In the last years, meshless or particle methods have attracted more and more attention. In many fields of numerical simulation these methods are on a par with classical methods or superior to them. In this work, we present the Finite Pointset Method (FPM) which uses a moving least squares particle approximation operator. The application of this method to various industrial problems at the Fraunhofer ITWM has shown that FPM is particularly suitable for highly dynamical problems with free surfaces and strongly changing geometries. Thereby, FPM offers exactly the features that we require for the analysis of the dynamics of solid bodies. In the present work, we provide a numerical scheme capable to simulate the behavior of elastic solids. We present the system of partial differential equations describing the dynamics of elastic solids and show its hyperbolic character. In particular, we focus our attention to the constitutive law for the stress tensor and provide evolution equations for the deviatoric part of the stress tensor in order to circumvent limitations of the classical Hooke's law. Furthermore, we present the basic principle of the Finite Pointset Method. In particular, we provide the concept of upwinding in a given direction as a key ingredient for stabilizing hyperbolic systems. The main part of this work describes the design of a numerical scheme based on FPM and an operator splitting to take the different processes within a solid body into account. Each resulting subsystem is treated separately in an adequate way. Hereby, we introduce the notion of system-inherent directions and dimensional upwinding. Finally, a coupling strategy for the subsystems and results are presented. We close this work with some final conclusions and an outlook on future work.

In this thesis we have discussed the problem of decomposing an integer matrix \(A\) into a weighted sum \(A=\sum_{k \in {\mathcal K}} \alpha_k Y^k\) of 0-1 matrices with the strict consecutive ones property. We have developed algorithms to find decompositions which minimize the decomposition time \(\sum_{k \in {\mathcal K}} \alpha_k\) and the decomposition cardinality \(|\{ k \in {\mathcal K}: \alpha_k > 0\}|\). In the absence of additional constraints on the 0-1 matrices \(Y^k\) we have given an algorithm that finds the minimal decomposition time in \({\mathcal O}(NM)\) time. For the case that the matrices \(Y^k\) are restricted to shape matrices -- a restriction which is important in the application of our results in radiotherapy -- we have given an \({\mathcal O}(NM^2)\) algorithm. This is achieved by solving an integer programming formulation of the problem by a very efficient combinatorial algorithm. In addition, we have shown that the problem of minimizing decomposition cardinality is strongly NP-hard, even for matrices with one row (and thus for the unconstrained as well as the shape matrix decomposition). Our greedy heuristics are based on the results for the decomposition time problem and produce better results than previously published algorithms.

Sterisch anspruchsvolle Cyclopentadienyl-Liganden wurden zur Stabilisierung neuer Mono(cyclopentadienyl) Verbindungen der schweren Erdalkalimetalle eingesetzt und deren Funktionalisierbarkeit dieser Spezies wurde exemplarisch durch die Synthese neutraler Tripeldecker-Sandwichkomplexe demonstriert. Die dabei ausgebildeten Molekülstrukturen lassen sich mittels DFT-Rechnungen zuverlässig vorhersagen. In diesem Zusammenhang wurde ebenfalls der Cyclononatetraenyl-Ligand, dessen Komplexeigenschaften bisher nur unzureichend untersucht wurden, eingesetzt. Im Rahmen dieser Arbeit gelang die Synthese des Bis(cyclononatetraenyl)bariums, Ba(C9H9)2, und dessen spektroskopische Charakterisierung. DFT-Rechnungen sagen für diesen Komplex eine Metallocenstruktur mit nahezu parallelen Ringen und einem Ba-Ring Abstand von 2.37 Å voraus. Durch den Einsatz des Tetraisopropylcyclopentadienyl (4Cp) und Tri(tert.-butyl)cyclopentadienyl (Cp’)-Liganden gelang die Synthese von Bis- und Monocyclopentadienyl-Verbindungen der frühen und späten Lanthanoide. Besonders interessant in diesem Zusammenhang ist die erfolgreiche Darstellung des Azido-Clusters, [Na(dme)3]2[4Cp6Yb6(N3)14] (4Cp= (Me2CH)4C5H), der die unterschiedlichen Koordinationsmöglichkeiten des Azido-Liganden in einem einzigen Komplex vereint. Vergleichbare Komplexe waren in der Organolanthanoidchemie bisher unbekannt. Durch Substitution am Cyclopentadienyl-System lassen sich dessen elektronische und sterische Eigenschaften signifikant verändern. Die Auswirkungen dieser Effekte können sehr eindrucksvoll an Manganocen-Komplexen demonstriert werden, in denen sich der low- und high-spin Zustand energetisch nur sehr wenig unterscheiden. Der elektronische Grundzustand einer Reihe unterschiedlich substituierter Manganocen-Komplexe wurde mittels Festkörpermagnetismus, ESR, Röntgenstrukturanalyse, EXAFS und variabler Temperatur UV-Vis Spektroskopie bestimmt, und mit dem Substitutionsmuster am Cyclopentadienyl-System korreliert. Spin-Gleichgewichte ließen sich für [(Me3C)C5H4]2Mn, [(Me3C)2C5H3]2Mn und [(Me3C)(Me3Si)C5H3]2Mn nachweisen. Theoretische Rechnungen postulieren, dass Cerocen, Ce(C8H8)2, ein Beispiel für Moleküle mit gemischt-konfiguriertem Grundzustand sei, der durch 80 % [(Ce)f1e2u(cot)e2u3] und 20 % [(Ce)f0e2u(cot)e2u4] beschreiben werden könne. Obwohl dieses Molekül bereits seit 1976 bekannt ist, ist dessen elektronische Struktur bis heute sehr umstritten. Im Rahmen dieser Arbeit wurden neue Synthesekonzepte für diese Verbindung entwickelt und die elektronische Struktur mittels magnetischer Messungen im Festkörper, EXAFS und XANES Studien untersucht. Die dabei erhaltenen Daten sind in sehr guter Übereinstimmung mit den theoretischen Rechnungen und belegen die Bedeutung eines gemischt-konfigurierten Grundzustandes bei der Bindung in Organometallkomplexen der f-Block Metalle. Während in Cerocen nur ein temperaturunabhängiger Paramagnetismus (TIP) beobachtet werden kann, findet man eine starke Temperaturabhängigkeit der magnetischen Suszeptibilität in Ytterbium Systemen des Typs Cp’2Yb(bipy’) [Cp´ und bipy´ sind substituierte Cyclopentadienyl- oder 4,4’-substituierter 2,2’-Bipyridyl-Liganden]. Temperaturabhängige XANES-Experimenten belegen, dass auch in diesen Systemen ein gemischt-konfigurierter Grundzustand vorliegt, der durch [(Yb)f14(bipy)b1()0] und [(Yb)f13(bipy)b1()1] beschreiben werden kann. Der relative Anteil beider Wellenfunktionen zum Grundzustand wird durch Substitution am 2,2’-Bipyridyl- oder Cyclopentadienyl-System signifikant beeinflusst. Modelle, mit denen sich dieses Verhalten qualitativ beschreiben lässt, wurden im Rahmen dieser Arbeit entwickelt. Ein kinetisch stabilisiertes, adduktfreies Titanocen wurde unter Verwendung des Di(tert.-butyl)cyclopentadienyl Liganden hergestellt und dessen Reaktivität gegenüber kleinen Molekülen, z.B. CO, N2 und H2 untersucht. Im Rahmen der Reaktivitätsstudien wurden ebenfalls 2,2’-Bipyridyl Addukte an das Cp’2Ti Fragment synthetisiert und deren magnetische Eigenschaften erforscht. Durch Variationen am 2,2’-Bipyridyl System lässt sich das Singlet-Triplet Splitting in diesem System gezielt steuern.

The aim of the thesis is the numerical investigation of saturated, stationary, incompressible Newtonian flow in porous media when inertia is not negligible. We focus our attention to the Navier-Stokes system with two pressures derived by two-scale homogenization. The thesis is subdivided into five Chapters. After the introductory remarks on porous media, filtration laws and upscaling methods, the first chapter is closed by stating the basic terminology and mathematical fundamentals. In Chapter 2, we start by formulating the Navier-Stokes equations on a periodic porous medium. By two-scale expansions of the velocity and pressure, we formally derive the Navier-Stokes system with two pressures. For the sake of completeness, known existence and uniqueness results are repeated and a convergence proof is given. Finally, we consider Stokes and Navier-Stokes systems with two pressures with respect to their relation to Darcy's law. Chapter 3 and Chapter 4 are devoted to the numerical solution of the nonlinear two pressure system. Therefore, we follow two approaches. The first approach which is developed in Chapter 3 is based on a splitting of the Navier-Stokes system with two pressures into micro and macro problems. The splitting is achieved by Taylor expanding the permeability function or by discretely computing the permeability function. The problems to be solved are a series of Stokes and Navier-Stokes problems on the periodicity cell. The Stokes problems are solved by an Uzawa conjugate gradient method. The Navier-Stokes equations are linearized by a least-squares conjugate gradient method, which leads to the solution of a sequence of Stokes problems. The macro problem consists of solving a nonlinear uniformly elliptic equation of second order. The least-squares linearization is applied to the macro problem leading to a sequence of Poisson problems. All equations will be discretized by finite elements. Numerical results are presented at the end of Chapter 3. The second approach presented in Chapter 4 relies on the variational formulation in a certain Hilbert space setting of the Navier-Stokes system with two pressures. The nonlinear problem is again linearized by the least-squares conjugate gradient method. We obtain a sequence of Stokes systems with two pressures. For the latter systems, we propose a fast solution method which relies on pre-computing Stokes systems on the periodicity cell for finite element basis functions acting as right hand sides. Finally, numerical results are discussed. In Chapter 5 we are concerned with modeling and simulation of the pressing section of a paper machine. We state a two-dimensional model of a press nip which takes into account elasticity and flow phenomena. Nonlinear filtration laws are incorporated into the flow model. We present a numerical solution algorithm and the chapter is closed by a numerical investigation of the model with special focus on inertia effects.

This thesis aims at an overall improvement of the diffusion coefficient predictions. For this reason the theoretical determination of diffusion, viscosity, and thermodynamics in liquid systems is discussed. Furthermore, the experimental determination of diffusion coefficients is also part of this work. All investigations presented are carried out for organic binary liquid mixtures. Diffusion coefficient data of 9 highly nonideal binary mixtures are reported over the whole concentration range at various temperatures, (25, 30, and 35) °C. All mixtures investigated in a Taylor dispersion apparatus consist of an alcohol (ethanol, 1-propanol, or 1-butanol) dissolved in hexane, cyclohexane, carbon tetrachloride, or toluene. The uncertainty of the reported data is estimated to be within 310-11 m2s-1. To compute the thermodynamic correction factor an excess Gibbs energy model is required. Therefore, the applicability of COSMOSPACE to binary VLE predictions is thoroughly investigated. For this purpose a new method is developed to determine the required molecular parameters such as segment types, areas, volumes, and interaction parameters. So-called sigma profiles form the basis of this approach which describe the screening charge densities appearing on a molecule’s surface. To improve the prediction results a constrained two-parameter fitting strategy is also developed. These approaches are crucial to guarantee the physical significance of the segment parameters. Finally, the prediction quality of this approach is compared to the findings of the Wilson model, UNIQUAC, and the a priori predictive method COSMO-RS for a broad range of thermodynamic situations. The results show that COSMOSPACE yields results of similar quality compared to the Wilson model, while both perform much better than UNIQUAC and COSMO-RS. Since viscosity influences also the diffusion process, a new mixture viscosity model has been developed on the basis of Eyring’s absolute reaction rate theory. The nonidealities of the mixture are accounted for with the thermodynamically consistent COSMOSPACE approach. The required model and component parameters are derived from sigma-profiles, which form the basis of the a priori predictive method COSMO-RS. To improve the model performance two segment parameters are determined from a least-squares analysis to experimental viscosity data, whereas a constraint optimisation procedure is applied. In this way the parameters retain their physical meaning. Finally, the viscosity calculations of this approach are compared to the findings of the Eyring-UNIQUAC model for a broad range of chemical mixtures. These results show that the new Eyring-COSMOSPACE approach is superior to the frequently employed Eyring-UNIQUAC method. Finally, on the basis of Eyring’s absolute reaction rate theory a new model for the Maxwell-Stefan diffusivity has been developed. This model, an extension of the Vignes equation, describes the concentration dependence of the diffusion coefficient in terms of the diffusivities at infinite dilution and an additional excess Gibbs energy contribution. This energy part allows the explicit consideration of thermodynamic nonidealities within the modelling of this transport property. If the same set of interaction parameters, which has been derived from VLE data, is applied for this part and for the thermodynamic correction, a theoretically sound modelling of VLE and diffusion can be achieved. The influence of viscosity and thermodynamics on the model accuracy is thoroughly investigated. For this purpose diffusivities of 85 binary mixtures consisting of alkanes, cycloalkanes, halogenated alkanes, aromatics, ketones, and alcohols are computed. The average relative deviation between experimental data and computed values is approximately 8 % depending on the choice of the gE-model. These results indicate that this model is superior to some widely used methods. In summary, it can be said that the new approach facilitates the prediction of diffusion coefficients. The final equation is mathematically simple, universally applicable, and the prediction quality is as good as other models recently developed without having to worry about additional parameters, like pure component physical property data, self diffusion coefficients, or mixture viscosities. In contrast to many other models, the influence of the mixture viscosity can be omitted. Though a viscosity model is not required in the prediction of diffusion coefficients with the new equation, the models presented in this work allow a consistent modelling approach of diffusion, viscosity, and thermodynamics in liquid systems.

Within the last decades, a remarkable development in materials science took place -- nowadays, materials are not only constructed for the use of inert structures but rather designed for certain predefined functions. This innovation was accompanied with the appearance of smart materials with reliable recognition, discrimination and capability of action as well as reaction. Even though ferroelectric materials serve smartly in real applications, they also possess several restrictions at high performance usage. The behavior of these materials is almost linear under the action of low electric fields or low mechanical stresses, but exhibits strong non-linear response under high electric fields or mechanical stresses. High electromechanical loading conditions result in a change of the spontaneous polarization direction with respect to individual domains, which is commonly referred to as domain switching. The aim of the present work is to develop a three-dimensional coupled finite element model, to study the rate-independent and rate-dependent behavior of piezoelectric materials including domain switching based on a micromechanical approach. The proposed model is first elaborated within a two-dimensional finite element setting for piezoelectric materials. Subsequently, the developed two-dimensional model is extended to the three-dimensional case. This work starts with developing a micromechanical model for ferroelectric materials. Ferroelectric materials exhibit ferroelectric domain switching, which refers to the reorientation of domains and occurs under purely electrical loading. For the simulation, a bulk piezoceramic material is considered and each grain is represented by one finite element. In reality, the grains in the bulk ceramics material are randomly oriented. This property is taken into account by applying random orientation as well as uniform distribution for individual elements. Poly-crystalline ferroelectric materials at un-poled virgin state can consequently be characterized by randomly oriented polarization vectors. Energy reduction of individual domains is adopted as a criterion for the initiation of domain switching processes. The macroscopic response of the bulk material is predicted by classical volume-averaging techniques. In general, domain switching does not only depend on external loads but also on neighboring grains, which is commonly denoted as the grain boundary effect. These effects are incorporated into the developed framework via a phenomenologically motivated probabilistic approach by relating the actual energy level to a critical energy level. Subsequently, the order of the chosen polynomial function is optimized so that simulations nicely match measured data. A rate-dependent polarization framework is proposed, which is applied to cyclic electrical loading at various frequencies. The reduction in free energy of a grain is used as a criterion for the onset of the domain switching processes. Nucleation in new grains and propagation of the domain walls during domain switching is modeled by a linear kinetics theory. The simulated results show that for increasing loading frequency the macroscopic coercive field is also increasing and the remanent polarization increases at lower loading amplitudes. The second part of this work is focused on ferroelastic domain switching, which refers to the reorientation of domains under purely mechanical loading. Under sufficiently high mechanical loading, however, the strain directions within single domains reorient with respect to the applied loading direction. The reduction in free energy of a grain is used as a criterion for the domain switching process. The macroscopic response of the bulk material is computed for the hysteresis curve (stress vs strain) whereby uni-axial and quasi-static loading conditions are applied on the bulk material specimen. Grain boundary effects are addressed by incorporating the developed probabilistic approach into this framework and the order of the polynomial function is optimized so that simulations match measured data. Rate dependent domain switching effects are captured for various frequencies and mechanical loading amplitudes by means of the developed volume fraction concept which relates the particular time interval to the switching portion. The final part of this work deals with ferroelectric and ferroelastic domain switching and refers to the reorientation of domains under coupled electromechanical loading. If this free energy for combined electromechanical loading exceeds the critical energy barrier elements are allowed to switch. Firstly, hysteresis and butterfly curves under purely electrical loading are discussed. Secondly, additional mechanical loads in axial and lateral directions are applied to the specimen. The simulated results show that an increasing compressive stress results in enlarged domain switching ranges and that the hysteresis and butterfly curves flatten at higher mechanical loading levels.

Metallocenes containing diarylethene type photochromic switches are synthesized, characterized and tested in polyolefin catalysts. Propylene polymerizations using unbridged bis(2,3-dibenzo[b]thiophen-3-yl)cyclopenta[b]thien-3-yl)zirconium dichloride/MAO (80) treated with 254nm UV irradiation produced bimodal polymer distributions by GPC. This was due to an increase in the low molecular weight fractions when the closed form of the catalyst/photoswitch was made. Comparison with similarly structured catalyst without photoisomerization properties did not produce bimodal polymer under identical conditions. Propylene polymerizations made with dimethylsilyl[(1,5-dimethyl-3-phenylcyclopenta[b]thien-6-yl)][(2,3-dibenzothien-3-yl)cyclopenta[b]thien-6-yl)]zirconium dichloride/MAO (86) with 254nm UV irradiation caused a 3 fold increase in the polymer molecular weight. Polymers made with ethylene and ethylene/hexene using (80) after UV irradiation did not show differences in measured polymer properties. Polymerizations with ethylene/ hexene mixtures using (86) had increased activity and co-monomer (hexene) incorporation with UV irradiation.