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In 2002, Korn and Wilmott introduced the worst-case scenario optimal portfolio approach.
They extend a Black-Scholes type security market, to include the possibility of a
crash. For the modeling of the possible stock price crash they use a Knightian uncertainty
approach and thus make no probabilistic assumption on the crash size or the crash time distribution.
Based on an indifference argument they determine the optimal portfolio process
for an investor who wants to maximize the expected utility from final wealth. In this thesis,
the worst-case scenario approach is extended in various directions to enable the consideration
of stress scenarios, to include the possibility of asset defaults and to allow for parameter
uncertainty.
Insurance companies and banks regularly have to face stress tests performed by regulatory
instances. In the first part we model their investment decision problem that includes stress
scenarios. This leads to optimal portfolios that are already stress test prone by construction.
The solution to this portfolio problem uses the newly introduced concept of minimum constant
portfolio processes.
In the second part we formulate an extended worst-case portfolio approach, where asset
defaults can occur in addition to asset crashes. In our model, the strictly risk-averse investor
does not know which asset is affected by the worst-case scenario. We solve this problem by
introducing the so-called worst-case crash/default loss.
In the third part we set up a continuous time portfolio optimization problem that includes
the possibility of a crash scenario as well as parameter uncertainty. To do this, we combine
the worst-case scenario approach with a model ambiguity approach that is also based on
Knightian uncertainty. We solve this portfolio problem and consider two concrete examples
with box uncertainty and ellipsoidal drift ambiguity.
Risk management is an indispensable component of the financial system. In this context, capital requirements are built by financial institutions to avoid future bankruptcy. Their calculation is based on a specific kind of maps, so-called risk measures. There exist several forms and definitions of them. Multi-asset risk measures are the starting point of this dissertation. They determine the capital requirements as the minimal amount of money invested into multiple eligible assets to secure future payoffs. The dissertation consists of three main contributions: First, multi-asset risk measures are used to calculate pricing bounds for European type options. Second, multi-asset risk measures are combined with recently proposed intrinsic risk measures to obtain a new kind of a risk measure which we call a multi-asset intrinsic (MAI) risk measure. Third, the preferences of an agent are included in the calculation of the capital requirements. This leads to another new risk measure which we call a scalarized utility-based multi-asset (SUBMA) risk measure.
In the introductory chapter, we recall the definition and properties of multi-asset risk
measures. Then, each of the aforementioned contributions covers a separate chapter. In
the following, the content of these three chapters is explained in more detail:
Risk measures can be used to calculate pricing bounds for financial derivatives. In
Chapter 2, we deal with the pricing of European options in an incomplete financial market
model. We use the common risk measures Value-at-Risk and Expected Shortfall to define
good deals on a financial market with log-normally distributed rates of return. We show that the pricing bounds obtained from Value-at-Risk may have a non-smooth behavior under parameter changes. Additionally, we find situations in which the seller's bound for a call option is smaller than the buyer's bound. We identify the missing convexity of the Value-at-Risk as main reason for this behavior. Due to the strong connection between the obtained pricing bounds and the theory of risk measures, we further obtain new insights in the finiteness and the continuity of multi-asset risk measures.
In Chapter 3, we construct the MAI risk measure. Therefore, recall that a multi-asset risk measure describes the minimal external capital that has to be raised into multiple eligible assets to make a future financial position acceptable, i.e., that it passes a capital adequacy test. Recently, the alternative methodology of intrinsic risk measures
was introduced in the literature. These ask for the minimal proportion of the financial position that has to be reallocated to pass the capital adequacy test, i.e., only internal capital is used. We combine these two concepts and call this new type of risk measure an MAI risk measure. It allows to secure the financial position by external capital as well as reallocating parts of the portfolio as an internal rebooking. We investigate several properties to demonstrate similarities and differences to the two
aforementioned classical types of risk measures. We find out that diversification reduces
the capital requirement only in special situations depending on the financial positions. With the help of Sion's minimax theorem we also prove a dual representation for MAI risk measures. Finally, we determine capital requirements in a model motivated by the Solvency II methodology.
In the final Chapter 4, we construct the SUBMA risk measure. In doing so, we consider the situation in which a financial institution has to satisfy a capital adequacy test, e.g., by the Basel Accords for banks or by Solvency II for insurers. If the financial situation of this institution is tight, then it can happen that no reallocation of the initial
endowment would pass the capital adequacy test. The classical portfolio optimization approach breaks down and a capital increase is needed. We introduce the SUBMA risk measure which optimizes the hedging costs and the expected utility of the institution simultaneously subject to the capital adequacy test. We find out that the SUBMA risk measure is coherent if the utility function has constant relative risk aversion and the capital adequacy test leads to a coherent acceptance set. In a one-period financial market model we present a sufficient condition for the SUBMA risk measure to be finite-valued and continuous. Finally, we calculate the SUBMA risk measure in a continuous-time financial market model for two benchmark capital adequacy tests.
By mapping the boundaries of Kant’s categorical imperative to the point where it permits the committing of a crime against Hume’s three principles of justice, it shall be demonstrated how far the area is in which these two concepts persist alongside each other and how narrow the border zone is in which they do not. Indeed, the latter is a forbidden place that can only be accessed through destiny and never by choice. Whoever is witnessed to stay there, must wish for Justice to draw her sword against him, and whoever dares to try reaching it, will only wander about a deserted land where both justice and morality are left behind.
This thesis reports about the investigation of di- and trinuclear coinage metal (Cu, Ag, Au) phosphine complexes with different anion adducts. Several mass spectrometric methods were utilized to investigate the complexes in gas phase without disturbing influences e.g. by the solvent. Electrospray Ionization (ESI) enabled the transfer of ions into the gas phase. In order to determine the fragmentation pathways and relative gas phase stabilities of these ions, Collision Induced Dissociation (CID) was used. The binding motifs and structures of the complexes were assigned by the help of Infrared (Multiple) Photon Dissociation (IR-(M)PD) at cryo (40 K, N2-tagged) and room temperature (300 K). Electron Transfer Dissociation/Reduction (ETD/R) was used to reduce the dicationic complexes to monocationic complexes. A tunable OPO/OPA laser system and the FELIX free-electron laser were used as IR laser sources. All experimental findings were supported by Density Functional Theory (DFT) calculation. In the first part of this thesis, the binding motifs and fragmentation behavior of the dinuclear coinage metal phosphine complexes with formate adduct were determined. Two different binding motifs were found and a stronger Cu-formate binding than in the case of Ag-formate. The dynamic bonding of hydrogen oxalate to phosphine ligand stabilized complexes were investigated in the second part. Several different binding motifs were determined. IR induced isomeric interconversions were found for the Ag complex whereas in case of the Cu complex a stiff hydrogen oxalate coordination seems to suppress such conversions. In the last part of this thesis, the ETD/R method was utilized to unravel the influence of oxidation states on the hydride and deuteride vibration modes of the trinuclear coinage metal complexes as well as the O2 adduct complexes and fragments with less complexity via IR-MPD and the FELIX free-electron laser. Unfortunately, an unambiguous assignment for the hydride and deuteride vibration modes is only possible for the fragments with less complexity.
The main objects of study in this thesis are abelian varieties and their endomorphism rings. Abelian varieties are not just interesting in their own right, they also have numerous applications in various areas such as in algebraic geometry, number theory and information security. In fact, they make up one of the best choices in public key cryptography and more recently in post-quantum cryptography. Endomorphism rings are objects attached to abelian varieties. Their computation plays an important role in explicit class field theory and in the security of some post-quantum cryptosystems.
There are subexponential algorithms to compute the endomorphism rings of abelian varieties of dimension one and two. Prior to this work, all these subexponential algorithms came with a probability of failure and additional steps were required to unconditionally prove the output. In addition, these methods do not cover all abelian varieties of dimension two. The objective of this thesis is to analyse the subexponential methods and develop ways to deal with the exceptional cases.
We improve the existing methods by developing algorithms that always output the correct endomorphism ring. In addition to that, we develop a novel approach to compute endomorphism rings of some abelian varieties that could not be handled before. We also prove that the subexponential approaches are simply not good enough to cover all the cases. We use some of our results to construct a family of abelian surfaces with which we build post-quantum cryptosystems that are believed to resist subexponential quantum attacks - a desirable property for cryptosystems. This has the potential of providing an efficient non interactive isogeny based key exchange protocol, which is also capable of resisting subexponential quantum attacks and will be the first of its kind.
Membrane proteins are of high pharmacological interest as they are involved in a variety of vital functions. However, to make them accessible to in vitro studies, they often need to be extracted from their natural lipid environment and stabilized with the aid of membrane-mimetic systems. Such membrane mimics can consist of diverse amphiphilic molecules. Small-molecule amphiphiles that can solubilize lipid bilayers, so-called detergents, have been invaluable tools for membrane-protein research in recent decades. Herein, novel small-molecule glyco-amphiphiles embodying three distinct design principles are introduced, and their biophysical and physicochemical properties are investigated. In doing so, the major aims consist in establishing new promising amphiphiles and in determining structure–efficacy relationships for their synthesis and application.
First, the software package D/STAIN was introduced to facilitate the analysis of demicellization curves obtained by isothermal titration calorimetry. The robustness of the underlying algorithm was demonstrated by analyzing demicellization curves representing large variations in amphiphile concentrations and thermodynamic parameters.
Second, the interactions of diastereomeric cyclopentane maltoside amphiphiles (CPMs) with lipid bilayers and membrane proteins were investigated. To this end, lipid model membranes, cellular membranes, and model membrane proteins were treated with different stereoisomer CPMs. These investigations pointed out the importance of stereochemical configuration in the solubilization of lipid bilayers, in the extraction of membrane proteins, and, ultimately, in the stabilization of the latter. Ultimately, CPM C12 could be identified as a particularly stabilizing agent.
Third, the influence of a polymerizable group attached to detergent-like amphiphiles was characterized regarding their micellization, micellar properties, and ability to solubilize lipid membranes. This revealed that such chemical modifications can have different degrees of impact regarding the investigated properties. In particular, micellization was influenced substantially, whereas the sizes of the resulting micelles varied slightly. The polymerizable amphiphiles were shown to solubilize artificial and natural lipid membranes and, consequently, to extract membrane proteins.
Last, the self-assembly of diglucoside amphiphiles bearing either a hydrocarbon or a lipophobic fluorocarbon chain to form native nanodiscs was investigated. It was shown that the presence of a fluorocarbon hydrophobic chain conveys superior stabilization properties onto the amphiphile and the resulting nanodiscs. Moreover, the kinetics of lipid exchange were fundamentally altered by the presence of the fluorocarbon amphiphiles in the nanodisc rim.
Industrial manufacturing companies have different IT control functions that can be represented with a so-called hierarchical automation pyramid. While these conventional software systems especially support the mass production with consistent demand, the future project “Industry 4.0” focuses on customer-oriented and adaptable production processes. In order to move from conventional production systems to a factory of the future, the control levels must be redistributed. With the help of cyber-physical production systems, an interoperable architecture must be, implemented which removes the hierarchical connection of the former control levels. The accompanied digitalisation of industrial companies makes the transition to modular production possible. At the same time, the requirements for production planning and control are increasing, which can be solved with approaches such as multi-agent systems (MASs). These software solutions are autonomous and intelligent objects with a distinct collaborative ability. There are different modelling methods, communication and interaction structures, as well as different development frameworks for these new systems. Since multi-agent systems have not yet been established as an industrial standard due to their high complexity, they are usually only tested in simulations. In this bachelor thesis, a detailed literature review on the topic of MASs in the field of production planning and control is presented. In addition, selected multi-agent approaches are evaluated and compared using specific classification criteria. In addition, the applicability of using these systems in digital and modular production is assessed.
In recent months, sustainable development and the achievement of the United Nations Sus- tainable Development Goals has gained unprecedented prominence. SDG 7 aspires to achieve access to electricity for the entire world population by 2030 and - at the same time - to significantly increase the share of renewable energy in the power mix. This target trans- lates into ambitious electricity supply and renewable energy asset growth scenarios for Sub- Saharan Africa, the least developed region worldwide. Though theoretical renewable energy potential is abundant and capital generally available, progress has been slow. Aside funds from donors and Development Finance Institutions, private commercial capital is required to accelerate the progress. Project Finance has successfully attracted private funds for renew- able energy assets in other jurisdictions but has played a negligible role in the energy tran- sition in Sub-Saharan Africa. A variety of reasons are identified that impede their implemen- tation, which are categorised into (i) unsatisfactory project pre-requisites and preparation, (ii) challenging host country conditions, (iii) elevated non-financial project risks and (iv) risky financial transaction structures. While a review of potential mitigation measures reveals that the risk factors are theoretically addressable, most require a multi-stakeholder alignment and exhibit some implementation complexity. Putting them into practice will therefore take time and will require a high level of commitment from host governments, sponsors, and fi- nancial institutions. While pressure and urgency are mounting, time will tell whether the pro- ject parties are more successful going forward.
In the field of measurement technology, the use of unmanned aerial vehicles is becoming more and more popular. For many measurement tasks, the use of such devices offers many advantages in terms of cost and measurement effort. However, the occurring vibrations and disturbances are a significant disadvantage for the application of these devices for several measurement tasks. Within the scope of this work, a platform for measurement devices is developed. The platform is designed specifically for use on drones. The task of the platform is to isolate measurement equipments mounted on it from the drone disturbances. For this purpose we go through the product development process according to VDI 2221 to design a mechanical model of the platform. Then, control strategies are applied to isolate the platform. Since the disturbances acting on a drone are not always stationary, two control strategies known for their ability to handle uncertain systems are used. One of them comes from the field of acoustic.
In dieser Arbeit wurden photoaktive Übergangsmetallkomplexe mit häufig vorkommenden Metallen wie Chrom, Vanadium und Kupfer untersucht. Hierbei wurden ausgewählte Exemplare mit besonders interessanten photophysikalischen und photochemischen Eigenschaften in Bezug auf praktische Anwendungen spektroskopisch charakterisiert. Über statische und insbesondere zeitaufgelöste FTIR- und Lumineszenzspektroskopie wurde ein tieferes Verständnis der Dynamik nach Lichtanregung erzielt. Das Hauptziel dieser Forschung besteht darin seltene und teure Elemente wie Ruthenium und Iridium gegen häufigere Metalle zu ersetzen.
In diesem Zusammenhang wurden mononukleare, oktaedrische Chrom(III)- und Vanadium(III)-Komplexe mit Polypyridylliganden, die im Arbeitskreis von Prof. Dr. Katja Heinze synthetisiert wurden, spektroskopisch charakterisiert. Diese Systeme zeigen vielversprechende Lumineszenzeigenschaften mit einer roten bzw. nahinfraroten Phosphoreszenz, wobei bei tiefen Temperaturen besonders hohe Quantenausbeuten und längere Lebensdauern beobachtet werden konnten.
Außerdem wurden einkernige Chrom(0)-, Molybdän(0)- und Wolfram(0)-Komplexe spektroskopisch charakterisiert, die allesamt im Arbeitskreis von Prof. Dr. Biprajit Sarkar synthetisiert wurden. Es sind mononukleare Komplexe mit Pyridyl-Carben-Liganden und Carbonyl-Coliganden mit einer dualen Phosphoreszenz (Emissionsbande im roten und nahinfraroten Bereich), wobei sich die niederenergetische Bande interessanterweise bis 1300 nm erstreckt. Außerdem zeigen die drei Komplexe bei intensiver Bestrahlung mit sichtbarem oder UV-Licht in organischer Lösung eine photochemische Reaktivität.
Als weitere vielversprechende Luminophore (sichtbare Emission) wurden Kupfer(I)-Komplexe analysiert, die für organische Leuchtdioden relevant sind. Einerseits wurden zweikernige Systeme mit einer zentralen Cu2I2-Einheit untersucht, die sich durch eine Fluorierung an den Phosphin-Hilfsliganden von den Derivaten aus Vorarbeiten unterscheiden. Die Systeme wurden im Arbeitskreis von Prof. Dr. Stefan Bräse zur Verbesserung der Löslichkeit im Vergleich zu unfluorierten Derivaten entwickelt. Die spektroskopischen Befunde dieser Arbeit zeigen, dass insbesondere die Einführung von Trifluormethylgruppen nicht nur die Löslichkeit, sondern auch die Stabilität verbessert. Andererseits wurden vierkernige Komplexe mit näherungsweise oktaedrischen Cu4X4-Clustern (X = I, Br, Cl) charakterisiert, wobei sich teilweise eine stark thermochrome Lumineszenz mit zwei klar separierten roten bzw. blauen Phosphoreszenzbanden ergab. Der Ursprung dieser Thermochromie konnte erstmalig auf experimentellem Weg den starken strukturellen Veränderung innerhalb des Cu4X4-Clusters zugeordnet werden.
Außerdem sind Kupfer(I)-Komplexe vielversprechende Kandidaten zur Verwendung als Photosensibilisatoren. Bei einem vom Arbeitskreis von Dr. Michael Karnahl zu Verfügung gestellten Kupfer(I)-Einkerner mit einem Liganden mit ausgedehntem 𝜋-System ergab sich ein langlebiger, nicht-strahlender Triplett-Zustand. In einem verwandten Projekt wurden ein- und zweikernige Kupfer(I)-Komplexe untersucht, die im Arbeitskreis von Dr. Claudia Bizzarri synthetisiert wurden. Der Fokus lag hierbei auf dem Einfluss einer Dimerisierung (kovalente Verbindung zweier mononuklearer Komplexe) oder einer Protonierung eines Liganden auf die photophysikalischen Eigenschaften.