Metal cluster aggregates of the composition Fen+/, Con+/-, Nin+/- and  [ConMm]+/- (M: Au, Rh and Pt) as model systems for catalytic C-H activation  and  structural determination of ionic dicarboxylic acids as model system for intramolecular hydrogen bonding

This thesis combines mass spectrometric studies on ionic dicarboxylic acids and transition metal cluster adsorbate complexes. IR-MPD spectra of protonated and deprotonated aliphatic and aromatic dicarboxylic acids provide insights in the nature of intramolecular hydrogen bonding. Investigations of their fragmentation behavior are supported by MP2 calculations. Prior work on cobalt transition metal clusters is extended to iron and nickel and three cobalt alloys have been studied.

Metadaten
Author:	Christine Merkert
URN:	urn:nbn:de:hbz:386-kluedo-37993
Advisor:	Gereon Niedner-Schatteburg
Document Type:	Doctoral Thesis
Language of publication:	English
Date of Publication (online):	2014/05/15
Year of first Publication:	2014
Publishing Institution:	Technische Universität Kaiserslautern
Granting Institution:	Technische Universität Kaiserslautern
Acceptance Date of the Thesis:	2014/03/27
Date of the Publication (Server):	2014/05/16
Page Number:	182
Faculties / Organisational entities:	Kaiserslautern - Fachbereich Chemie
DDC-Cassification:	5 Naturwissenschaften und Mathematik / 540 Chemie
Licence (German):	Standard gemäß KLUEDO-Leitlinien vom 10.09.2012